Product ID:MIXSTD1A-100, MIXED CALIBRATION STANDARD-CAL (SUPDAT)
MSDS Date:02/23/1994
FSC:6630
NIIN:00N060359
MSDS Number: BXSWH

SPEX INDUSTRIES INC

3880 PARK AVE
EDISON, NJ 08820
US

Emergency Phone: 800-424-9300(CHEMTREC)

Info Phone: 908-549-7144

Preparer: VANAJA SIVAKUMAR

Cage: 07977

SPEX CERTIPREP INC

METUCHEN, NJ 08840 US

Telephone: 732-549-7144

Cage: 07977

NITRIC ACID; (HNO*3) (SARA 302/313) (CERCLA) (CONTAINING

CAS: 7697-37-2

RTECS: QU5775000

Fraction By Weight: 5%

OSHA PEL 2 PPM

ACGIH TLV: 2 PPM;4 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

100 PPM.

CAS: 7440-38-2

RTECS: CG0525000

Fraction By Weight: <0.1%

OSHA PEL SEE 1910.1018

ACGIH TLV: 0.01 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

100 PPM.

CAS: 1305-78-8

RTECS: EW3100000

Fraction By Weight: <0.1%

OSHA PEL 5 MG/M3

ACGIH TLV: 2 MG/M3

ANTIMONY (SARA 313) (CERCLA). %50 PPM.

CAS: 7440-36-0

RTECS: CC4025000

Fraction By Weight: <0.1%

OSHA PEL 0.5 MG/M3

ACGIH TLV: 0.5 MG/M3 (SB)

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

50 PPM.

CAS: 7782-49-2

RTECS: VS7700000

Fraction By Weight: <0.1%

OSHA PEL 0.2 MG/M3

ACGIH TLV: 0.2 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

20 PPM.

CAS: 7440-42-8

RTECS: ED7350000

Fraction By Weight: <0.1%

OSHA PEL 10 MG/M3 (B2O3)

ACGIH TLV: 10 MG/M3 (B2O3)

20 PPM.

CAS: 7440-43-9

RTECS: EU9800000

Fraction By Weight: <0.1%

OSHA PEL 0.2 MG/M3 DUST

ACGIH TLV: 0.01 MG/M3 DUST

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

20 PPM.

CAS: 7440-50-8

RTECS: GL5325000

Fraction By Weight: <0.1%

OSHA PEL 0.1MG/M3 FUME;1 DUST

ACGIH TLV: 0.2 MG/M3 FUME

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

20 PPM.

CAS: 7439-96-5

RTECS: OO9275000

Fraction By Weight: <0.1%

OSHA PEL 5 MG/M3 DUST, C

ACGIH TLV: 5 MG/M3 DUST

10 PPM.

CAS: 7440-39-3

RTECS: CQ8370000

Fraction By Weight: <0.1%

OSHA PEL 0.5 MG/M3

ACGIH TLV: N/K

SILVER (SARA 313) (CERCLA). %5 PPM.

CAS: 7440-22-4

RTECS: VW3500000

Fraction By Weight: <0.1%

OSHA PEL 0.01 MG/M3

ACGIH TLV: 0.1 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 90-95%

OSHA PEL N/K

ACGIH TLV: N/K

VIOLENT SPLATTERING.

RTECS: 9999999ZZ

EXPOS. INGEST OF LIQ WILL CAUSE IMMED PAIN

RTECS: 9999999ZZ

FATAL CAUSING SPASM, INFLAMM & EDEMA OF LARYNX &

RTECS: 9999999ZZ

SENSATION, COUGHING, WHEEZING, LARYNGITIS, SHORTNESS

RTECS: 9999999ZZ

& FULL LENGTH FACESHIELD .

RTECS: 9999999ZZ

OF AN EYE WASH IN CASE OF EMERGENCY.

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:SYMPS & HLTH HAZS FOR DILUTE NITRIC
ACID ARE EXPECTED TO BE LESS SEV THAN EXPOS TO CONC NITRIC ACID.
HOWEVER, SINCE NITRIC ACID IS IN SOLN AT 1% OR GREATER, HLTH HAZS
FOR CONC NITRIC ACID ARE GIVEN. C ONC NITRIC ACID MAY BE FATAL IF
TOO MUCH IS INHALED/ABSORBED THRU SKIN. CONC NITRIC ACID VAP/MIST
IS AN(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:IRRIT OF EYES, MUC MEMBS & SKIN. IN
CONT W/EYES, IT PRDCES SEV BURNS WHICH MAY RSLT IN PERM DMG &
VISUAL IMPAIRMENT. ON SKIN, LIQ/CONC VAP PRDCES IMMED, SEV &
PENETRATING BURNS; CONC SOLNS CA USE DEEP ULCERS & STAIN SKIN
BRIGHT YELLOW/YELLOWISH BROWN COLOR. VAP & MIST MAY ERODE EXPOS
TEETH W/PRLNG (ING 14)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES:FLUSH W/WATER FOR AT LEAST 15 MINUTES OCCAS LIFTING
UPPER & LOWER EYELIDS. SKIN:REMOVE CONTAM CLOTHING, THEN FLUSH
W/WATER FOR AT LEAST 15 MINUTES. WASH CLOTHING THORO BEFORE REUSE.
INHAL:MOVE TO FRESH AIR. INGEST:DO NOT INDUCE VOMITING. GET MED
ATTN IMMEDIATELY. ONLY IF VICTIM IS CONSCIOUS, GIVE LARGE AMOUNTS
OF WATER OR MILK. IF IRRITATION CONTINUES, GET MEDICAL ATTENTION
IMMEDIATELY.

Extinguishing Media:APPROPRIATE TO SURROUNDING FIRE CONDITIONS.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:CONC HNO*3 IS NOT COMBUST, BUT IS STRONG
OXIDIZER & ITS HEAT OF RXN W/REDUCING AGENTS/COMBUSTS MAY CAUSE
IGNIT. CAN REACT W/METALS TO RELS FLAMM (SUPP DATA)

Spill Release Procedures:VENT AREA. DILUTE SPILL W/WATER & NEUT W/SODA
ASH, LIMESTONE, ETC. WIPE UP & PUT INTO SEALED CNTNR FOR PROPER
DISP. WASH SPILL SITE OFF W/WATER AFTER MATL PICK UP IS COMPLETE.
WEAR CHEM RESIST GLASSES , GLOVES & CLTHG. WEAR NIOSH/MSHA APPRVD
RESP.
Neutralizing Agent:SODA ASH, LIMESTONE, ETC.

Handling and Storage Precautions:CONC NITRIC ACID WILL ATTACK SOME
FORMS OF PLASTICS, RUBBER & COATINGS. STORE AT ROOM TEMP. KEEP
TIGHTLY SEALED WHEN NOT IN USE.
Other Precautions:IRRITANT, OXIDIZER & CORROSIVE LIQUID. AVOID
INHALATION, INGESTION & CONTACT W/EYES & SKIN.

Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE IN A CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS(ING 17)
Other Protective Equipment:DELUGE SHOWER WHICH MEETS ANSI DESIGN
CRITERIA . WEAR CHEM RESIST CLTHG, LAB COAT. HAVE IMMED
AVAILABILITY(ING 18)
Work Hygienic Practices:WASH CAREFULLY AFTER USE.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO:SOLUTION 1. EXPLO HAZ:HYDROGEN GAS. CONC HNO*3
REACTS EXPLOSIVELY W/COMBUST ORG/READILY OXIDIZABLE MATLS SUCH AS;
ALCOHOL, WOOD, TURPENTINE, METAL PWDRS, HYDROGEN SULFIDE, ETC .
MATLS TO AVOID:ALCOHOL, WOOD, TURPENTINE, METAL PWDRS, HYDROGEN
SULFIDE, ETC. CONT W/STRONG BASES WILL CAUSE (ING 13)

Spec Gravity:1
Solubility in Water:SOLUBLE
Appearance and Odor:TRANSPARENT W/ACRID ODOR.

Stability Indicator/Materials to Avoid:YES
CONC HNO*3 IS POWERFUL OXIDIZING AGENT. IT REACTS EXPLOSIVELY W/COMBUST
ORG/READILY OXIDIZABLE MATLS SUCH AS; (SUPDAT)
Stability Condition to Avoid:ELEVATED TEMPERATURES MAY CAUSE CONTAINERS
TO BURST & LIBERATE TOXIC OXIDES OF NITROGEN.
Hazardous Decomposition Products:WILL RELEASE TOXIC NITROGEN OXIDE
FUMES & VAPORS.

Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS . CONTACT LOCAL HAZARDOUS OR CHEMICAL WASTE DISPOSAL
AGENCY FOR REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.